The group known as Associates in Arc Jewel first appeared on December 30, 2012, under the name Lovely★Doll. They were later renamed Love☆Ken on December 24, 2013. On February 2, 2014, the unit was split into two groups: Luce and Stella. The group's name was then changed to Luce Twinkle Wink☆ on May 23, 2014.
The group also participated in Animelo Summer Live 2015 -THE GATE- as backdancers for fripSide. They made their major debut via NBC Universal Entertainment Japan with Koiiro♡Shikoukairo on November 25, 2015. The members of the group include Usami Yukino (Twinkle Pink), Saori Itayama (Twinkle Water Blue), Kaho Higaki (Twinkle Lavender), Saki Fukasawa (Twinkle Red), and Megumi Nishikiori (Twinkle Yellow). Some of these members were originally from other groups, such as Rusuban Girls and coro☆coro.